Phosphazene-cored star polymer bearing redox-active side groups as a cathode-active material in Li-ion batteries

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dc.contributor.authorAydin, Muhammet
dc.contributor.authorGorur, Mesut
dc.contributor.authorYilmaz, Faruk
dc.date.accessioned2025-10-29T11:23:29Z
dc.date.issued2016
dc.departmentFakülteler, Temel Bilimler Fakültesi, Kimya Bölümü
dc.description.abstractA new hexa-armed star polymer bearing 2,2,6,6-tetramethylpiperidine-1-oxyl (TEMPO)-pending polymer chains emanating from a phosphazene core (P2) was prepared and used as the cathode material in Li-ion battery assembly. The properties of the assembled battery (BP2) were compared with those of BL2 assembled using its linear counterpart (L2). Their spin concentrations investigated via solution electron spin resonance (ESR) measurements were found to be almost the same. The charge/discharge capacities and energy densities of BP2 were considerably higher than those of BL2. However, they exhibited comparable charge/discharge efficiencies and their discharge capacities dropped to similar percentages of their initial values. (C) 2016 Elsevier B.V. All rights reserved.
dc.description.sponsorshipScientific and Technological Research Council of Turkey (TUBITAK) [114Z302]
dc.description.sponsorshipThe authors thank the Scientific and Technological Research Council of Turkey (TUBITAK) for the financial support (Grant number: 114Z302)
dc.identifier.doi10.1016/j.reactfunctpolym.2016.02.008
dc.identifier.endpage19
dc.identifier.issn1381-5148
dc.identifier.issn1873-166X
dc.identifier.orcid0000-0002-8716-9970
dc.identifier.scopus2-s2.0-84960889574
dc.identifier.scopusqualityQ1
dc.identifier.startpage11
dc.identifier.urihttps://doi.org/10.1016/j.reactfunctpolym.2016.02.008
dc.identifier.urihttps://hdl.handle.net/20.500.14854/9463
dc.identifier.volume102
dc.identifier.wosWOS:000375737300002
dc.identifier.wosqualityQ1
dc.indekslendigikaynakWeb of Science
dc.indekslendigikaynakScopus
dc.language.isoen
dc.publisherElsevier Science Bv
dc.relation.ispartofReactive & Functional Polymers
dc.relation.publicationcategoryMakale - Uluslararası Hakemli Dergi - Kurum Öğretim Elemanı
dc.rightsinfo:eu-repo/semantics/closedAccess
dc.snmzKA_WOS_20251020
dc.subjectOrganic radical battery
dc.subjectNitroxy stable free radical
dc.subjectAtom transfer radical polymerization
dc.subjectStar polymer
dc.subjectRedox-active polymer
dc.titlePhosphazene-cored star polymer bearing redox-active side groups as a cathode-active material in Li-ion batteries
dc.typeArticle

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