The diverse behaviour of the P-Cl bonds in the spiro-cis-ansa spermidine derivative cyclotriphosphazene towards mono-functional nucleophilic reagents

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dc.contributor.authorIbisoglu, Hanife
dc.contributor.authorTemur, Basak
dc.contributor.authorUn, Ilker
dc.date.accessioned2025-10-29T11:23:21Z
dc.date.issued2009
dc.departmentFakülteler, Temel Bilimler Fakültesi, Kimya Bölümü
dc.description.abstractA number of new spiro-ansa spermidine derivative cyclotriphosphazenes (2-10) is synthesized in order to provide insight into the reaction mechanism for nucleophilic substitution. The structures of the compounds were determined by elemental analysis, mass (MS), H-1, F-19 (for 9) and P-31 NMR spectroscopies. Compounds (2-8) and 9, 10 can be formed by a proton abstraction-chloride elimination and both the S-N(1) and S-N(2) reaction mechanisms, respectively. (C) 2009 Elsevier B.V. All rights reserved.
dc.description.sponsorshipGIT Research Fund
dc.description.sponsorshipThe author thanks the Shin Nisso Kako Co. Ltd. for gifts of N3P3Cl6, Professor Adem Kilic (Gebze Institute of Technology, GIT), Professors Robert A. Shaw and David B. Davies (Birkbeck College, University of London) for helpful discussions and GIT Research Fund for partial support.
dc.identifier.doi10.1016/j.saa.2009.06.010
dc.identifier.endpage335
dc.identifier.issn1386-1425
dc.identifier.issue2
dc.identifier.pmid19581120
dc.identifier.scopus2-s2.0-69249232257
dc.identifier.scopusqualityQ1
dc.identifier.startpage329
dc.identifier.urihttps://doi.org/10.1016/j.saa.2009.06.010
dc.identifier.urihttps://hdl.handle.net/20.500.14854/9420
dc.identifier.volume74
dc.identifier.wosWOS:000270109300004
dc.identifier.wosqualityQ2
dc.indekslendigikaynakWeb of Science
dc.indekslendigikaynakScopus
dc.indekslendigikaynakPubMed
dc.language.isoen
dc.publisherPergamon-Elsevier Science Ltd
dc.relation.ispartofSpectrochimica Acta Part A-Molecular and Biomolecular Spectroscopy
dc.relation.publicationcategoryMakale - Uluslararası Hakemli Dergi - Kurum Öğretim Elemanı
dc.rightsinfo:eu-repo/semantics/closedAccess
dc.snmzKA_WOS_20251020
dc.subjectCyclotriphosphazene
dc.subjectNucleophilic substitution
dc.subjectPhosphazene
dc.subjectP-31 NMR
dc.subjectSpermidine
dc.subjectReaction mechanism
dc.subjectF-19 NMR
dc.titleThe diverse behaviour of the P-Cl bonds in the spiro-cis-ansa spermidine derivative cyclotriphosphazene towards mono-functional nucleophilic reagents
dc.typeArticle

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