Resorcinarene-mono-benzimidazolium salts as NHC ligands for Suzuki-Miyaura cross-couplings catalysts

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dc.contributor.authorIsci, Umit
dc.contributor.authorAygun, Muhittin
dc.contributor.authorSevincek, Resul
dc.contributor.authorZorlu, Yunus
dc.contributor.authorDumoulin, Fabienne
dc.date.accessioned2025-10-29T11:08:21Z
dc.date.issued2015
dc.departmentFakülteler, Temel Bilimler Fakültesi, Kimya Bölümü
dc.description.abstractTwo mono-benzimidazolium salts of resorcinarene have been prepared and used as ligands in Suzuki-Miyaura cross-coupling reactions. They have been fully characterized by H-1 and C-13 NMR, MALDI, and FT-IR spectroscopic methods, and their structures were confirmed by X-ray diffraction analysis. These two new resorcinarene-based monobenzimidazolium salts showed good catalytic activity for coupling reactions in DMF. The highest conversion was achieved for arylation of 4-bromotoluene using the resorcinarenyl mono-dimethylbenzimidazolium salt.
dc.identifier.doi10.3906/kim-1506-50
dc.identifier.endpageU277
dc.identifier.issn1300-0527
dc.identifier.issue6
dc.identifier.orcid0000-0001-9670-9062
dc.identifier.orcid0000-0002-6285-0524
dc.identifier.orcid0000-0003-2811-1872
dc.identifier.orcid0000-0002-0388-8338
dc.identifier.scopus2-s2.0-84958974172
dc.identifier.scopusqualityQ3
dc.identifier.startpage1300
dc.identifier.urihttps://doi.org/10.3906/kim-1506-50
dc.identifier.urihttps://hdl.handle.net/20.500.14854/5327
dc.identifier.volume39
dc.identifier.wosWOS:000365507600016
dc.identifier.wosqualityQ3
dc.indekslendigikaynakWeb of Science
dc.indekslendigikaynakScopus
dc.language.isoen
dc.publisherTubitak Scientific & Technological Research Council Turkey
dc.relation.ispartofTurkish Journal of Chemistry
dc.relation.publicationcategoryMakale - Uluslararası Hakemli Dergi - Kurum Öğretim Elemanı
dc.rightsinfo:eu-repo/semantics/openAccess
dc.snmzKA_WOS_20251020
dc.subjectSuzuki-Miyaura reaction
dc.subjectresorcinarene
dc.subjectcavitand
dc.subjectN-heterocyclic carbene
dc.subjectbenzimidazolium salt
dc.subjectcatalyst
dc.titleResorcinarene-mono-benzimidazolium salts as NHC ligands for Suzuki-Miyaura cross-couplings catalysts
dc.typeArticle

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