Silver and proton driven fluorescent multiple-mode molecular logic gates employing phthalocyanines

Abstract

Spectral properties and switch behavior of two alkyl thia units bearing Zn (II) phthalocyanine derivatives (Pc-A and Pc-B) were investigated in solvents and in solid matrix of ethyl cellulose by means of absorption and emission spectroscopy. Fluorescence lifetime and fluorescence quantum yield values of the Zn (II) phthalocyanines were calculated. The employed phthalocyanines demonstrated multiple molecular logic gate functions operated by H(+) and Ag(+) ions as chemical inputs. The silver driven fluorescence modulation of the Pc-A arises from reversible variations in emission signal intensity at 717 nm. The Pc-B exhibited a similar decreasing emission response to proton and silver ions and an accompanying increasing peak yielding an isobestic point at 746 nm upon protonation. The phthalocyanine doped thin films selectively responded to silver ions in sub-nano and/or pico molar levels. Observed detection limits were 7.6 x 10(-12) and 2.3 x 10(-11) M for Pc-A and Pc-B, respectively. In immobilized phases the attained reversible relative signal changes of Pc-A and Pc-B were 82 and 90%, respectively. (C) 2010 Elsevier B.V. All rights reserved.