Hydrophobic poly(alkoxysilane) organogels as sorbent material for oil spill cleanup

Basit Öğe Kaydı
dc.contributor.authorAydin, Gulsah Ozan
dc.contributor.authorSonmez, Hayal Bulbul
dc.date.accessioned2025-10-29T11:24:37Z
dc.date.issued2015
dc.departmentFakülteler, Temel Bilimler Fakültesi, Kimya Bölümü
dc.description.abstractIn this study, reusable poly(alkoxysilane) organogels with high absorption capacities were synthesized by the condensation of a cyclo aliphatic glycol (UNOXOL (TM)) and altering the chain length of the alkyltriethoxysilanes. The structural and thermal properties of cross-linked poly(alkoxysilane) polymers were determined by FTIR, solid-state C-13 and Si-29 CPMAS NMR and TGA. The oil absorbency of poly(alkoxysilane)s was determined through oil absorption tests, absorption and desorption kinetics. Results showed that the highest oil absorbency capacities were found to be 295% for hexane, 389% for euro diesel, 428% for crude oil, 652% for gasoline, 792% for benzene, 792% for toluene, 868% for tetrahydrofuran, and 1060% for dichloromethane for the poly(alkoxysilane) gels based on UNOXOL (TM) and dodecyltriethoxysilane. Owing to their hydrophobic structure, the poly(alkoxysilane) organogels can selectively absorb crude oil from water. The reusability of the absorbents was quantitatively investigated, demonstrating that absorbents can be used effectively at least nine times. (C) 2015 Elsevier Ltd. All rights reserved.
dc.description.sponsorshipScientific and Technological Research Council of Turkey-TUBITAK [TBAG/111T098]
dc.description.sponsorshipWe thank the Scientific and Technological Research Council of Turkey-TUBITAK for the support of this work through Grant TBAG/111T098, the Turkish Petroleum Refineries Co.-TUPRAS for supplying of crude oil samples and the Dow Chemical Company, USA for supplying mixture of 1,3-1,4-cyclohexanedimethanol (UNOXOL (TM)) monomer.
dc.identifier.doi10.1016/j.marpolbul.2015.05.033
dc.identifier.endpage164
dc.identifier.issn0025-326X
dc.identifier.issn1879-3363
dc.identifier.issue1-2
dc.identifier.pmid26002096
dc.identifier.scopus2-s2.0-84931569548
dc.identifier.scopusqualityQ1
dc.identifier.startpage155
dc.identifier.urihttps://doi.org/10.1016/j.marpolbul.2015.05.033
dc.identifier.urihttps://hdl.handle.net/20.500.14854/10038
dc.identifier.volume96
dc.identifier.wosWOS:000357348900029
dc.identifier.wosqualityQ1
dc.indekslendigikaynakWeb of Science
dc.indekslendigikaynakScopus
dc.indekslendigikaynakPubMed
dc.language.isoen
dc.publisherPergamon-Elsevier Science Ltd
dc.relation.ispartofMarine Pollution Bulletin
dc.relation.publicationcategoryMakale - Uluslararası Hakemli Dergi - Kurum Öğretim Elemanı
dc.rightsinfo:eu-repo/semantics/closedAccess
dc.snmzKA_WOS_20251020
dc.subjectPoly(alkoxysilane) organogel
dc.subjectUNOXOL (TM)
dc.subjectAlkyltriethoxysilane
dc.subjectOil absorbency
dc.subjectOil spill
dc.subjectReusability
dc.titleHydrophobic poly(alkoxysilane) organogels as sorbent material for oil spill cleanup
dc.typeArticle

Dosyalar

Koleksiyon

WoS İndeksli Yayınlar Koleksiyonu
PubMed İndeksli Yayınlar Koleksiyonu
Scopus İndeksli Yayınlar Koleksiyonu
Temel Bilimler Fakültesi Koleksiyonu