Preparation of iron phthalocyanine complex bearing four tetraazamacrocycles as a precursor for oxidation catalyst with two catalytic sites

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dc.contributor.authorIsci, Uemit
dc.contributor.authorGurek, Ayse Guel
dc.contributor.authorAhsen, Vefa
dc.contributor.authorSorokin, Alexander B.
dc.date.accessioned2025-10-29T11:13:16Z
dc.date.issued2009
dc.departmentFakülteler, Temel Bilimler Fakültesi, Kimya Bölümü
dc.description.abstractThe synthesis of the iron phthalocyanine bearing four fused tetraaza macrocycles starting from N,N',N '',N'''-tetrakis(p-tolylsulfonyl)triethylenetetraamine and 1,2-dibromo-4,5-bis-(bromomethyl) benzene is reported. The exchange of protecting tosyl groups by acetyl groups was necessary to obtain iron phthalocyanine. The efficiency of iron phthalocyanine as oxidation catalyst was tested for the practically important oxidation of 2,3,6-trimethylphenol (TMP) at different reaction conditions.
dc.description.sponsorshipCNRS-TUBITAK [U/61(102T212]
dc.description.sponsorshipThis work was supported by the CNRS-TUBITAK funding [(TBAG-U/61(102T212)]project number). The binational French-Turkish doctoral fellowship for Umit Isci from the Embassy of France in Ankara is gratefully acknowledged.
dc.identifier.doi10.1142/S1088424609000851
dc.identifier.endpage752
dc.identifier.issn1088-4246
dc.identifier.issn1099-1409
dc.identifier.issue6
dc.identifier.orcid0000-0002-6285-0524
dc.identifier.scopus2-s2.0-68949091777
dc.identifier.scopusqualityQ3
dc.identifier.startpage747
dc.identifier.urihttps://doi.org/10.1142/S1088424609000851
dc.identifier.urihttps://hdl.handle.net/20.500.14854/6661
dc.identifier.volume13
dc.identifier.wosWOS:000268843600009
dc.identifier.wosqualityQ2
dc.indekslendigikaynakWeb of Science
dc.indekslendigikaynakScopus
dc.language.isoen
dc.publisherWorld Sci Publ Co Inc
dc.relation.ispartofJournal of Porphyrins and Phthalocyanines
dc.relation.publicationcategoryMakale - Uluslararası Hakemli Dergi - Kurum Öğretim Elemanı
dc.rightsinfo:eu-repo/semantics/closedAccess
dc.snmzKA_WOS_20251020
dc.subjecttetraazamacrocycle
dc.subjectiron phthalocyanine
dc.subjecttrimethylphenol (TMP)
dc.subjectoxidation
dc.subjectcatalyst
dc.titlePreparation of iron phthalocyanine complex bearing four tetraazamacrocycles as a precursor for oxidation catalyst with two catalytic sites
dc.typeArticle

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