Effect of iodine substitution pattern on the singlet oxygen generation and solvent depended keto-enol tautomerization behavior of BODIPY photosensitizers

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dc.contributor.authorKoksoy, Baybars
dc.contributor.authorKaya, Esra Nur
dc.contributor.authorHacivelioglu, Ferda
dc.contributor.authorYeşilot, Serkan
dc.contributor.authorDurmuş, Mahmut
dc.date.accessioned2025-10-29T11:28:02Z
dc.date.issued2017
dc.departmentFakülteler, Temel Bilimler Fakültesi, Kimya Bölümü
dc.description.abstractThe novel iodinated-BODIPY derivatives (la and 1c) containing one or three iodine atoms were synthesized for the first time. The photochemical and photophysical properties of these BODIPYs were investigated and results were compared with two (lb) and four (1d) iodine bearing BODIPY derivatives. Surprisingly, the addition of iodine atoms to the meso-aryl positions of the phenyl moiety caused a color change due to the transformation of the enol form of the aromatic OH group to its keto form depending on the using solvent. This solvent affected keto-enol tautomerization on the BODIPY compounds was determined for the first time.
dc.description.sponsorshipScientific and Technological Research Council of Turkey (TUBITAK) [114Z924]
dc.description.sponsorshipThis work was supported by a project from the Scientific and Technological Research Council of Turkey (TUBITAK) (Project number: 114Z924).
dc.identifier.doi10.1016/j.dyepig.2017.01.067
dc.identifier.endpage391
dc.identifier.issn0143-7208
dc.identifier.issn1873-3743
dc.identifier.orcid0000-0001-7939-5380
dc.identifier.orcid0000-0002-3614-3770
dc.identifier.scopus2-s2.0-85012247220
dc.identifier.scopusqualityQ1
dc.identifier.startpage384
dc.identifier.urihttps://doi.org/10.1016/j.dyepig.2017.01.067
dc.identifier.urihttps://hdl.handle.net/20.500.14854/11031
dc.identifier.volume140
dc.identifier.wosWOS:000395212100046
dc.identifier.wosqualityQ1
dc.indekslendigikaynakWeb of Science
dc.indekslendigikaynakScopus
dc.language.isoen
dc.publisherElsevier Sci Ltd
dc.relation.ispartofDyes and Pigments
dc.relation.publicationcategoryMakale - Uluslararası Hakemli Dergi - Kurum Öğretim Elemanı
dc.rightsinfo:eu-repo/semantics/closedAccess
dc.snmzKA_WOS_20251020
dc.subjectBODIPY
dc.subjectIodination
dc.subjectFluorescence
dc.subjectSinglet oxygen
dc.subjectPhotodynamic therapy
dc.subjectKeto-enol tautomerization
dc.titleEffect of iodine substitution pattern on the singlet oxygen generation and solvent depended keto-enol tautomerization behavior of BODIPY photosensitizers
dc.typeArticle

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