E-peroxone process for the treatment of laundry wastewater: A case study

Abstract

The treatment of laundry wastewater by ozonation, electro-oxidation (EOX), electro-oxidation with oxygen sparging (EOX with O-2 sparging) and the combined electro-peroxone (E-peroxone) process was investigated. E-peroxone process is based on the production of H2O2 electrochemically from O-2 in sparged ozone generator effluent (O-2 and O-3 gas mixture) using carbon-polytetrafluorethylene (carbon-PTFE) cathodes. The electro-generated H2O2 then reacts with sparged O-3 to produce % OH. The concentration of H2O2 and % OH was determined as similar to 10 g L1- and 0.1567 mu M in the E-peroxone process, respectively. While no % OH was produced in EOX, the measured % OH concentration was 0.1872 mu M in the ozonation process, which is greater than E-peroxone. All advanced processes adopted in this study effectively removed turbidity. Although, E-peroxone was not highly effective in eliminating chemical oxygen demand (COD) from laundry wastewater, it removed almost 77% methylene blue active substance (MBAS), whereas EOX and ozonation processes removed 86% MBAS. Besides, anion concentration increased dramatically during E-peroxone treatment. This suggests that E-peroxone is insufficient to remove inorganics. Regarding the toxicity analysis, the lowest toxicity was observed in E-peroxone process as the inhibition rate was reduced to 22.45% from 80.64%. Moreover, specific energy consumption (SEC) values were calculated as 0.003, 0.079 and 0.067 kWh kg(-1) for EOX, ozonation and E-peroxone, respectively. Hence, E-peroxone was found to be more cost-effective than ozonation in this case. However, EOX was found to be the most cost-effective process for laundry wastewater treatment.