Exceptionally effective generation of singlet oxygen in aqueous media via iodinated zinc-phthalocyanine

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dc.contributor.authorGhazal, Basma
dc.contributor.authorHusain, Ali
dc.contributor.authorGanesan, Asaithampi
dc.contributor.authorDurmuş, Mahmut
dc.contributor.authorZhang, Xian-Fu
dc.contributor.authorMakhseed, Saad
dc.date.accessioned2025-10-29T11:28:01Z
dc.date.issued2019
dc.departmentFakülteler, Temel Bilimler Fakültesi, Kimya Bölümü
dc.description.abstractAsymmetrically substituted zinc phthalocyanine (Pc) derivatives bearing quatemized triazolyl moieties for water solubility and iodine as a heavy metal atom have been investigated as singlet oxygen generators in aqueous media. In addition to the heavy atom effect exerted by iodine covalently bonded to the Pc molecule, a second dimensional effect induced by aggregation which brings the iodine anions of triazolyl units into closer proximity to the Pc core leading to the highest reported singlet oxygen generation for a Pc derivative in water (Phi(Delta) = 0.87).
dc.description.sponsorshipKuwait Foundation for the Advancement of Science [P114-14-SC01]
dc.description.sponsorshipRSP unit general facilities of the Faculty of Science GFS [GS 01/01, GS 02/01, GS 03/01, GS 01/03, GS 01/05, GS 02/13]
dc.description.sponsorshipThis work was financially support by the Kuwait Foundation for the Advancement of Science (Grant Number P114-14-SC01) and the RSP unit general facilities of the Faculty of Science GFS (GS 01/01, GS 02/01, GS 03/01, GS 01/03, GS 01/05, GS 02/13). We thank the Chemistry department at Kuwait University for use of the MALDI-TOF mass spectrometer.
dc.identifier.doi10.1016/j.dyepig.2019.01.036
dc.identifier.endpage304
dc.identifier.issn0143-7208
dc.identifier.issn1873-3743
dc.identifier.orcid0000-0003-0069-085X
dc.identifier.orcid0000-0002-3239-5524
dc.identifier.orcid0000-0001-5150-6317
dc.identifier.scopus2-s2.0-85060887739
dc.identifier.scopusqualityQ1
dc.identifier.startpage296
dc.identifier.urihttps://doi.org/10.1016/j.dyepig.2019.01.036
dc.identifier.urihttps://hdl.handle.net/20.500.14854/11023
dc.identifier.volume164
dc.identifier.wosWOS:000460718200040
dc.identifier.wosqualityQ1
dc.indekslendigikaynakWeb of Science
dc.indekslendigikaynakScopus
dc.language.isoen
dc.publisherElsevier Sci Ltd
dc.relation.ispartofDyes and Pigments
dc.relation.publicationcategoryMakale - Uluslararası Hakemli Dergi - Kurum Öğretim Elemanı
dc.rightsinfo:eu-repo/semantics/closedAccess
dc.snmzKA_WOS_20251020
dc.subjectPhotodynamic Therapy
dc.subjectMetal Phthalocyanines
dc.subjectIn-Vitro
dc.subjectPhotosensitizers
dc.subjectCancer
dc.titleExceptionally effective generation of singlet oxygen in aqueous media via iodinated zinc-phthalocyanine
dc.typeArticle

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