Synthesis and characterization of a new meso-tetra-dihydro benzocyclobutacenaphthylene free-base porphyrin

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dc.contributor.authorIsci, Umit
dc.contributor.authorTopal, Sevinc Zehra
dc.contributor.authorOnal, Emel
dc.contributor.authorFidan, Ismail
dc.contributor.authorBerber, Savas
dc.contributor.authorAhsen, Vefa
dc.contributor.authorParejo, Concepcion
dc.date.accessioned2025-10-29T11:13:08Z
dc.date.issued2018
dc.departmentFakülteler, Temel Bilimler Fakültesi, Kimya Bölümü
dc.departmentFakülteler, Temel Bilimler Fakültesi, Fizik Bölümü
dc.description.abstractA meso-tetra-6b, 10b-dihydrobenzo[j]cyclobut[a] acenaphthylene free-base porphyrin was synthesised and its photophysical, photochemical and electrochemical properties were compared with those of free-base meso-tetraphenylporphyrin. The frontier orbitals and the HOMO-LUMO energy gaps of both compounds were also determined. It was demonstrated that the meso6b, 10b-Dihydrobenzo[j]cyclobut[a] acenaphthylene porphyrin retained the same properties as the tetraphenylporphyrin.
dc.description.sponsorshipMinisterio de Economia Industria y Competitividad of Spain [CTQ2014-55798-R]
dc.description.sponsorshipSupport from the Ministerio de Economia Industria y Competitividad of Spain (CTQ2014-55798-R) is gratefully acknowledged. The calculations were performed at TRUBA resources.
dc.identifier.doi10.1142/S1088424618500062
dc.identifier.endpage180
dc.identifier.issn1088-4246
dc.identifier.issn1099-1409
dc.identifier.issue1-3
dc.identifier.orcid0000-0002-0388-8338
dc.identifier.orcid0000-0001-5535-2829
dc.identifier.orcid0000-0002-6285-0524
dc.identifier.scopus2-s2.0-85042747376
dc.identifier.scopusqualityQ3
dc.identifier.startpage173
dc.identifier.urihttps://doi.org/10.1142/S1088424618500062
dc.identifier.urihttps://hdl.handle.net/20.500.14854/6618
dc.identifier.volume22
dc.identifier.wosWOS:000427932100019
dc.identifier.wosqualityQ3
dc.indekslendigikaynakWeb of Science
dc.indekslendigikaynakScopus
dc.language.isoen
dc.publisherWorld Scientific Publ Co Pte Ltd
dc.relation.ispartofJournal of Porphyrins and Phthalocyanines
dc.relation.publicationcategoryMakale - Uluslararası Hakemli Dergi - Kurum Öğretim Elemanı
dc.rightsinfo:eu-repo/semantics/closedAccess
dc.snmzKA_WOS_20251020
dc.subjectporphyrin
dc.subject6b
dc.subject10b-dihydrobenzo[j]cyclobut[a] acenaphthylene
dc.subjecttetraphenylporphyrin
dc.titleSynthesis and characterization of a new meso-tetra-dihydro benzocyclobutacenaphthylene free-base porphyrin
dc.typeArticle

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