The reactions of phenoxy substituted phosphazenes with 1,3-propanediol and 3-amino-1-propanol

Abstract

In the present work, two phenoxy substituted phosphazene derivatives, 2-(2,4,6-tri-tert-butylphenoxo)-2,4,4,6,6-pentachlorocyclo-2 lambda(5), 4 lambda(5), 6 lambda(5)-triphosphazatriene (1) and 2-(2,4,6-tri-methylphenoxo)-2,4,4,6,6-pentachlorocyclo-2 lambda(5), 4 lambda(5), 6 lambda(5)-triphosphazatriene, were prepared. The reactions of these derivatives with 3-amino-1-propanol (3) and 1,3-propanediol (4) were studied. Novel phenoxy-substituted; two mono spiro (5, 8), and two dispiro phosphazene derivatives (6, 7) were synthesized. The structures of the compounds were defined by elemental analysis, IR, H-1 and P-31 NMR spectroscopy.