Photophysical, photochemical properties of chalcone substituted Zinc(II) and Magnesium(II) metallophthalocyanines bearing thiophene units

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dc.contributor.authorKamiloglu, Ayse Aktas
dc.contributor.authorOmeroglu, Ipek
dc.contributor.authorYalazan, Halise
dc.contributor.authorDurmuş, Mahmut
dc.contributor.authorCelik, Gonca
dc.contributor.authorKantekin, Halit
dc.date.accessioned2025-10-29T11:32:46Z
dc.date.issued2022
dc.departmentFakülteler, Temel Bilimler Fakültesi, Kimya Bölümü
dc.description.abstractThe novel thiophene-chalcone compound (2), phthalonitrile derivatives bearing thiophene-chalcone group (3 and 4) and their zinc (II) (ZnPcs) (3a and 4a) and magnesium (II) (MgPcs) (3b and 4b) phthalocyanine compounds were synthesized in this study. The structure of all these new compounds were elucidated by spectroscopic techniques like IR, (1) H NMR, (13) C NMR (for compounds 2, 3 and 4), MALDI-TOF mass and UV-Vis. The fluorescence quantum yields and lifetimes (photophysical properties), and the singlet oxygen and photodegradation quantum yields (photochemical properties) of thiophene bearing chalcone substituted ZnPcs (3a and 4a) and MgPcs (3b and 4b) were studied in DMSO (dimethylsulfoxide) to determine if they are convenient photosensitizers for photodynamic therapy (PDT) applications.
dc.description.sponsorshipScientific&Technological Research Council of Turkey (TUBITAK) [:118Z578]
dc.description.sponsorshipThis study was supported by the Scientific&Technological Research Council of Turkey (TUBITAK), Project no:118Z578.
dc.identifier.doi10.1007/s10847-022-01152-3
dc.identifier.endpage703
dc.identifier.issn1388-3127
dc.identifier.issn1573-1111
dc.identifier.issue7-8
dc.identifier.orcid0000-0002-7347-4018
dc.identifier.orcid0000-0002-7528-0911
dc.identifier.scopus2-s2.0-85132840915
dc.identifier.scopusqualityQ2
dc.identifier.startpage693
dc.identifier.urihttps://doi.org/10.1007/s10847-022-01152-3
dc.identifier.urihttps://hdl.handle.net/20.500.14854/12116
dc.identifier.volume102
dc.identifier.wosWOS:000817063500001
dc.identifier.wosqualityQ3
dc.indekslendigikaynakWeb of Science
dc.indekslendigikaynakScopus
dc.language.isoen
dc.publisherSpringer
dc.relation.ispartofJournal of Inclusion Phenomena and Macrocyclic Chemistry
dc.relation.publicationcategoryMakale - Uluslararası Hakemli Dergi - Kurum Öğretim Elemanı
dc.rightsinfo:eu-repo/semantics/closedAccess
dc.snmzKA_WOS_20251020
dc.subjectPhthalocyanine
dc.subjectThiophene
dc.subjectPhotophysicochemical
dc.subjectFluorescence
dc.subjectSinglet oxygen
dc.titlePhotophysical, photochemical properties of chalcone substituted Zinc(II) and Magnesium(II) metallophthalocyanines bearing thiophene units
dc.typeArticle

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