The synthesis, thermal and photophysical properties of phenoxycyclotriphosphazenyl-substituted cyclic and polymeric phosphazenes

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dc.contributor.authorCosut, Buenyemin
dc.contributor.authorHacivelioglu, Ferda
dc.contributor.authorDurmuş, Mahmut
dc.contributor.authorKilic, Adem
dc.contributor.authorYeşilot, Serkan
dc.date.accessioned2025-10-29T11:23:43Z
dc.date.issued2009
dc.departmentFakülteler, Temel Bilimler Fakültesi, Kimya Bölümü
dc.description.abstractAn hydroxyl substituted hexa(phenoxy)cyclotriphosphazene (3) is reacted with hexachlorocyclotriphosphazene, N3P3Cl6, octachlorocyclotetraphosphazene, N4P4Cl8 and poly(dichlorophosphazene), (Cl2P=N)(n), to give cyclic compounds (4 and 5) and a polymeric compound (6). The newly synthesised compounds have been fully characterised by elemental analysis, MALDI-TOF mass spectrometry, gel permeation chromatography (6), FT-IR, H-1, C-13 and P-31 NMR spectroscopy. The thermal stability and fluorescence spectral properties of all these novel compounds have been investigated. It was found that the thermal stability and fluorescence spectral properties of cyclic compounds 4 and 5 are superior to those of compound 6. (C) 2009 Elsevier Ltd. All rights reserved.
dc.description.sponsorshipGebze Institute of Technology (GIT)
dc.description.sponsorshipWe thank the Gebze Institute of Technology (GIT) Research Fund for partial financial support.
dc.identifier.doi10.1016/j.poly.2009.05.027
dc.identifier.endpage2516
dc.identifier.issn0277-5387
dc.identifier.issue12
dc.identifier.orcid0000-0003-2181-2457
dc.identifier.orcid0000-0001-6530-0205
dc.identifier.orcid0000-0002-3614-3770
dc.identifier.scopus2-s2.0-67650125557
dc.identifier.scopusqualityQ2
dc.identifier.startpage2510
dc.identifier.urihttps://doi.org/10.1016/j.poly.2009.05.027
dc.identifier.urihttps://hdl.handle.net/20.500.14854/9598
dc.identifier.volume28
dc.identifier.wosWOS:000268994200029
dc.identifier.wosqualityQ2
dc.indekslendigikaynakWeb of Science
dc.indekslendigikaynakScopus
dc.language.isoen
dc.publisherPergamon-Elsevier Science Ltd
dc.relation.ispartofPolyhedron
dc.relation.publicationcategoryMakale - Uluslararası Hakemli Dergi - Kurum Öğretim Elemanı
dc.rightsinfo:eu-repo/semantics/closedAccess
dc.snmzKA_WOS_20251020
dc.subjectCyclophosphazene
dc.subjectPolyphosphazene
dc.subjectP-31 NMR
dc.subjectThermal stability
dc.subjectFluorescence
dc.titleThe synthesis, thermal and photophysical properties of phenoxycyclotriphosphazenyl-substituted cyclic and polymeric phosphazenes
dc.typeArticle

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