Phosphorylation of 2-Aryl Quinoxaline Derivatives via C-H/P-H Cross Coupling under Transition-Metal-Free Conditions

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dc.contributor.authorKarimi-Nami, Rahman
dc.contributor.authorAdib, Mehdi
dc.contributor.authorHeydari, Forouzan
dc.contributor.authorRajai-Daryasarei, Saeideh
dc.contributor.authorKarakaya, Idris
dc.date.accessioned2025-10-29T11:17:02Z
dc.date.issued2022
dc.departmentFakülteler, Temel Bilimler Fakültesi, Kimya Bölümü
dc.description.abstractIn this study, we have developed an efficient protocol for synthesis of phosphorus-substituted heterocycles through reaction between 2-Aryl quinoxalines and dialkyl phosphites under transition-metal-free conditions. Here, K2S2O8 has been used as the sole oxidant for the facile synthesis of phosphorus substituted derivates. A variety of heteroaryl phosphonate derivatives have been synthesized under optimized conditions in good to excellent yields with this facile and environment friendly protocol.
dc.description.sponsorshipResearch Council of the University of Tehran
dc.description.sponsorshipThis research was supported by the Research Council of the University of Tehran.
dc.identifier.doi10.1080/10406638.2021.1983619
dc.identifier.endpage6416
dc.identifier.issn1040-6638
dc.identifier.issn1563-5333
dc.identifier.issue9
dc.identifier.orcid0000-0002-3590-7206
dc.identifier.orcid0000-0003-2152-4340
dc.identifier.orcid0000-0003-0418-2211
dc.identifier.scopus2-s2.0-85115696123
dc.identifier.scopusqualityQ2
dc.identifier.startpage6411
dc.identifier.urihttps://doi.org/10.1080/10406638.2021.1983619
dc.identifier.urihttps://hdl.handle.net/20.500.14854/7865
dc.identifier.volume42
dc.identifier.wosWOS:000700005900001
dc.identifier.wosqualityQ3
dc.indekslendigikaynakWeb of Science
dc.indekslendigikaynakScopus
dc.language.isoen
dc.publisherTaylor & Francis Ltd
dc.relation.ispartofPolycyclic Aromatic Compounds
dc.relation.publicationcategoryMakale - Uluslararası Hakemli Dergi - Kurum Öğretim Elemanı
dc.rightsinfo:eu-repo/semantics/openAccess
dc.snmzKA_WOS_20251020
dc.subjectPhosphorus-substituted heterocycles
dc.subject2-Aryl quinoxalines
dc.subjectdialkyl phosphites
dc.subjectC-H activitaion
dc.titlePhosphorylation of 2-Aryl Quinoxaline Derivatives via C-H/P-H Cross Coupling under Transition-Metal-Free Conditions
dc.typeArticle

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