Mesoporous TiO2-rutile supported MnxOy-Na2WO4: Preparation, characterization and catalytic performance in the oxidative coupling of methane

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dc.contributor.authorYildiz, Mahmut
dc.date.accessioned2025-10-29T11:26:39Z
dc.date.issued2019
dc.departmentFakülteler, Temel Bilimler Fakültesi, Kimya Bölümü
dc.description.abstractThe oxidative coupling of methane (OCM) is one of the most important direct method to convert natural gas into value added products. For the first time in literature mesoporous TiO2-rutile supported MnxOy-Na2WO4 catalyst was prepared, characterized and tested in the OCM. The activity parameters (X-CH4, S-C-2, Y-C-2) did not change substantially during the reaction and they were mostly stable. The MnxOy-Na2WO4/mes-TiO2-rutile catalyst seems to have promising potential for the OCM. Moreover, when it is compared with commercial TiO2-rutile and TiO2-anatase supported catalysts in literature, it can be concluded that it is a candidate showing even better performance in the OCM. (C) 2019 The Korean Society of Industrial and Engineering Chemistry. Published by Elsevier B.V. All rights reserved.
dc.description.sponsorshipScientific and Technological Research Council of Turkey, TUBITAK [115Z877]
dc.description.sponsorshipThis work was financially supported by the Scientific and Technological Research Council of Turkey, TUBITAK (Grant number: 115Z877). I would like to thank Prof. Dr. Serap Besli for laboratory facilities. I would like to thank Prof. Dr. Reinhard Schomacker from Technische Universitat Berlin for allowing me to use the high throughput reactor system for catalytic activity tests. I also thank Adem Sen for XRD measurements, Ahmet Nazim for SEM-EDX analyses and Ibrahim Fazil Sengul for TG analyses.
dc.identifier.doi10.1016/j.jiec.2019.04.016
dc.identifier.endpage499
dc.identifier.issn1226-086X
dc.identifier.issn1876-794X
dc.identifier.scopus2-s2.0-85064949293
dc.identifier.scopusqualityQ1
dc.identifier.startpage488
dc.identifier.urihttps://doi.org/10.1016/j.jiec.2019.04.016
dc.identifier.urihttps://hdl.handle.net/20.500.14854/10355
dc.identifier.volume76
dc.identifier.wosWOS:000470939700046
dc.identifier.wosqualityQ1
dc.indekslendigikaynakWeb of Science
dc.indekslendigikaynakScopus
dc.institutionauthorYildiz, Mahmut
dc.language.isoen
dc.publisherElsevier Science Inc
dc.relation.ispartofJournal of Industrial and Engineering Chemistry
dc.relation.publicationcategoryMakale - Uluslararası Hakemli Dergi - Kurum Öğretim Elemanı
dc.rightsinfo:eu-repo/semantics/closedAccess
dc.snmzKA_WOS_20251020
dc.subjectMnxOy-Na2WO4
dc.subjectTiO2
dc.subjectRutile
dc.subjectOxidative coupling of methane
dc.subjectOCM
dc.subjectEthylene
dc.subjectDirect methane conversion
dc.subjectMesoporous metal oxide
dc.subjectSupport material
dc.titleMesoporous TiO2-rutile supported MnxOy-Na2WO4: Preparation, characterization and catalytic performance in the oxidative coupling of methane
dc.typeArticle

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