Utilization of machine learning algorithms in estimation of syngas fractions and exergy values for gasification of biomass-lignite mixtures in fixed and fluidized bed gasifiers

dc.contributor.authorCakar, Mislina
dc.contributor.authorInsel, Mert Akin
dc.contributor.authorSadikoglu, Hasan
dc.contributor.authorYucel, Ozgun
dc.date.accessioned2025-10-29T11:27:38Z
dc.date.issued2025
dc.departmentFakülteler, Temel Bilimler Fakültesi, Kimya Bölümü
dc.description.abstractEarth's environmental challenges, such as climate change and pollution, require urgent emission reductions. A thermochemical method that transforms carbon-rich substances into syngas, biomass gasification produces clean hydrogen as a sustainable energy carrier. This process ensures high carbon conversion efficiency while minimizing greenhouse gas emissions. This study examines the gasification of nine biomass-lignite blends using fluidized-bed and fixed-bed gasifiers. A wide range of biomass samples blended with lignite enabled the analysis of different sample characteristics and their impact on the gasification technique. ASPEN Plus (R) simulations assess the effects of biomass-to-lignite ratio, equivalence ratio (ER), steam to biomass ratio (SBR), and reactor temperature on syngas fraction and system efficiency. Machine learning models gaussian process regression (GPR), random forest (RF), support vector machine (SVM), and decision tree (DT) predict syngas and product gas exergy values, providing a data-driven optimization approach. For hazelnut shell validation, R2 values were 0.98 for the fixed-bed model and 0.96 for the fluidized-bed model. The Random Forest algorithm demonstrated the highest accuracy (R2 = 0.93), outperforming other models. The study also analysed the amount of data required and demonstrated robust models capable of learning with limited data. Since a significant portion of the machine learning process involves dataset creation, the ability to learn from small datasets is crucial. This highlights the significance of data-efficient learning in machine learning applications. Findings contribute to advancing biomass gasification for cleaner hydrogen production.
dc.description.sponsorshipTUBITAK [123M784]
dc.description.sponsorshipYildiz Technical University's Scientific Research Projects Council [FBA_2023_5648]
dc.description.sponsorshipThe research was funded by TUBITAK (Project No: 123M784) and Yildiz Technical University's Scientific Research Projects Council (Project No: FBA_2023_5648) . The authors sincerely appreciate the support provided by these institutions.
dc.identifier.doi10.1016/j.fuel.2025.135883
dc.identifier.issn0016-2361
dc.identifier.issn1873-7153
dc.identifier.scopus2-s2.0-105007415379
dc.identifier.scopusqualityQ1
dc.identifier.urihttps://doi.org/10.1016/j.fuel.2025.135883
dc.identifier.urihttps://hdl.handle.net/20.500.14854/10842
dc.identifier.volume401
dc.identifier.wosWOS:001510725000001
dc.identifier.wosqualityQ1
dc.indekslendigikaynakWeb of Science
dc.indekslendigikaynakScopus
dc.language.isoen
dc.publisherElsevier Sci Ltd
dc.relation.ispartofFuel
dc.relation.publicationcategoryMakale - Uluslararası Hakemli Dergi - Kurum Öğretim Elemanı
dc.rightsinfo:eu-repo/semantics/openAccess
dc.snmzKA_WOS_20251020
dc.subjectBiomass and lignite blends
dc.subjectBiomass gasification
dc.subjectExergy
dc.subjectData generation
dc.subjectMachine learning
dc.titleUtilization of machine learning algorithms in estimation of syngas fractions and exergy values for gasification of biomass-lignite mixtures in fixed and fluidized bed gasifiers
dc.typeArticle

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