Optimized synthesis and crystal growth by sublimation of 1,3,3-trichloroisoindolenines, key building blocks for crosswise phthalocyanines

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dc.contributor.authorAyhan, Mehmet Menaf
dc.contributor.authorZorlu, Yunus
dc.contributor.authorGokdemir, Ozlem
dc.contributor.authorGürek, Ayşe Gül
dc.contributor.authorDumoulin, Fabienne
dc.contributor.authorAhsen, Vefa
dc.contributor.authorHirel, Catherine
dc.date.accessioned2025-10-29T11:20:10Z
dc.date.issued2014
dc.departmentFakülteler, Temel Bilimler Fakültesi, Kimya Bölümü
dc.description.abstractAmong possible asymmetrically substituted phthalocyanines, ABAB derivatives remain rare. Their selective synthesis is based on the use of trichloroisoindolenines, so far remaining tedious to obtain. An optimized synthesis of 1,3,3-trichloroisoindolenine 1 and 1,3,3,6,7-pentachloroisoindolenine 2 is reported. An original crystallization method based on crystal growth by sublimation was eminently suitable regarding the air-sensitivity of these derivatives and allowed their thorough crystallographic characterization.
dc.description.sponsorshipThe Scientific and Technological Research Council of Turkey [108 M034]
dc.description.sponsorshipThe Scientific and Technological Research Council of Turkey (project 108 M034) is gratefully acknowledged.
dc.identifier.doi10.1039/c4ce00189c
dc.identifier.endpage6563
dc.identifier.issn1466-8033
dc.identifier.issue29
dc.identifier.orcid0000-0002-4500-7594
dc.identifier.orcid0000-0003-2811-1872
dc.identifier.orcid0000-0002-0388-8338
dc.identifier.orcid0000-0001-5367-2220
dc.identifier.scopus2-s2.0-84903748353
dc.identifier.scopusqualityQ2
dc.identifier.startpage6556
dc.identifier.urihttps://doi.org/10.1039/c4ce00189c
dc.identifier.urihttps://hdl.handle.net/20.500.14854/8454
dc.identifier.volume16
dc.identifier.wosWOS:000339172600009
dc.identifier.wosqualityQ1
dc.indekslendigikaynakWeb of Science
dc.indekslendigikaynakScopus
dc.language.isoen
dc.publisherRoyal Soc Chemistry
dc.relation.ispartofCrystengcomm
dc.relation.publicationcategoryMakale - Uluslararası Hakemli Dergi - Kurum Öğretim Elemanı
dc.rightsinfo:eu-repo/semantics/closedAccess
dc.snmzKA_WOS_20251020
dc.subjectNonlinear-Optical Properties
dc.subjectChemistry
dc.subjectSubstituents
dc.subjectPorphyrins
dc.subjectCatalysts
dc.titleOptimized synthesis and crystal growth by sublimation of 1,3,3-trichloroisoindolenines, key building blocks for crosswise phthalocyanines
dc.typeArticle

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