Novel zinc(II) phthalocyanine conjugates bearing different numbers of BODIPY and iodine groups as substituents on the periphery

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dc.contributor.authorGol, Cem
dc.contributor.authorMalkoc, Mustafa
dc.contributor.authorYeşilot, Serkan
dc.contributor.authorDurmuş, Mahmut
dc.date.accessioned2025-10-29T11:28:04Z
dc.date.issued2014
dc.departmentFakülteler, Temel Bilimler Fakültesi, Kimya Bölümü
dc.description.abstractThe novel zinc (II) phthalocyanine (Pc)-boron dipyrromethene (BODIPY) conjugates bearing one, two, three or four BODIPY units on the phthalocyanine framework were synthesized by the reaction of 4,4'-difluoro-8-(4-ethynyl)-phenyl-1,3,5,7-tetramethyl-4-bora-3a,4a-diaza-s-indacene (Ethynyl-BODIPY) with 2(3),9(10),16(17),23(24)-tetrakis(iodo) zinc(II) phthalocyanine (Iodo-Pc) using the Pd catalyzed Sonogashira-coupling reaction. The newly synthesized Pc-BODIPY conjugates were fully characterized by elemental analysis, H-1 and C-13 NMR, MALDI-TOF mass, FT-IR, UV-Vis and fluorescence spectroscopic techniques. The photophysical and photochemical properties of these conjugates were investigated by means of absorption and fluorescence spectroscopies in DMSO solutions for the determination of their photodynamic therapy (PDT) efficiency. The photoinduced energy transfer process of these novel conjugates was also explored in tetrahydrofuran solution. (C) 2014 Elsevier Ltd. All rights reserved.
dc.description.sponsorshipScientific and Technological Research Council of Turkey (TUBITAK) [TBAG-111T066]
dc.description.sponsorshipThis study was supported by the Scientific and Technological Research Council of Turkey (TUBITAK) (Project No: TBAG-111T066).
dc.identifier.doi10.1016/j.dyepig.2014.06.003
dc.identifier.endpage90
dc.identifier.issn0143-7208
dc.identifier.issn1873-3743
dc.identifier.orcid0000-0001-9258-1866
dc.identifier.scopus2-s2.0-84903155760
dc.identifier.scopusqualityQ1
dc.identifier.startpage81
dc.identifier.urihttps://doi.org/10.1016/j.dyepig.2014.06.003
dc.identifier.urihttps://hdl.handle.net/20.500.14854/11040
dc.identifier.volume111
dc.identifier.wosWOS:000340976400012
dc.identifier.wosqualityQ1
dc.indekslendigikaynakWeb of Science
dc.indekslendigikaynakScopus
dc.language.isoen
dc.publisherElsevier Sci Ltd
dc.relation.ispartofDyes and Pigments
dc.relation.publicationcategoryMakale - Uluslararası Hakemli Dergi - Kurum Öğretim Elemanı
dc.rightsinfo:eu-repo/semantics/closedAccess
dc.snmzKA_WOS_20251020
dc.subjectAsymmetric phthalocyanine
dc.subjectBODIPY
dc.subjectPanchromatic
dc.subjectFluorescence
dc.subjectEnergy transfer
dc.subjectSinglet oxygen
dc.titleNovel zinc(II) phthalocyanine conjugates bearing different numbers of BODIPY and iodine groups as substituents on the periphery
dc.typeArticle

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