A high selective “Turn-Off” aminopyrene based cyclotriphosphazene fluorescent chemosensors for Fe3+/Cu2+ ions

dc.contributor.authorŞenkuytu, Elif
dc.date.accessioned2025-10-29T12:07:57Z
dc.date.issued2018
dc.departmentGebze Teknik Üniversitesi
dc.description.abstractIn this current study, the new aminopyrene based cyclotriphosphazene chemosensors 6 and 7 have been successfully synthesized. The identity of all the synthesized cyclotriphosphazene compounds was proven by 1H, 31P NMR and MALDI-TOF mass spectrometry. The photophysical and metal sensing properties of the targeted compounds were determined in the presence of various metals (Li+, Na+, K+, Cs+, Mg2+, Ca2+, Ba2+, Mn2+, Fe3+, Cr3+, Co2+, Ni2+, Cu2+, Cd2+, Al3+, Hg+, Zn2+) using fluorescence spectroscopy. The fluorescence titration results showed that compounds 6 and 7 can be used as fluorescent chemosensors with high selectivity and sensitivity for Cu2+ and Fe3+ ions. Also, the complex stoichiometry of the final cyclotriphosphazene chemosensors and Cu2+/Fe3+ ions was determined by a Job's plot. © 2020 Elsevier B.V., All rights reserved.
dc.identifier.doi10.1016/j.ica.2018.04.028
dc.identifier.endpage65
dc.identifier.issn0020-1693
dc.identifier.scopus2-s2.0-85046021292
dc.identifier.scopusqualityQ2
dc.identifier.startpage58
dc.identifier.urihttps://doi.org/10.1016/j.ica.2018.04.028
dc.identifier.urihttps://hdl.handle.net/20.500.14854/14195
dc.identifier.volume479
dc.indekslendigikaynakScopus
dc.institutionauthorŞenkuytu, Elif
dc.language.isoen
dc.publisherElsevier S.A.
dc.relation.ispartofInorganica Chimica Acta
dc.relation.publicationcategoryMakale - Uluslararası Hakemli Dergi - Kurum Öğretim Elemanı
dc.rightsinfo:eu-repo/semantics/closedAccess
dc.snmzKA_Scopus_20251020
dc.subject1-Aminopyrene
dc.subjectCyclotriphosphazenes
dc.subjectFe3+/Cu2+
dc.subjectFluorescent chemosensor
dc.titleA high selective “Turn-Off” aminopyrene based cyclotriphosphazene fluorescent chemosensors for Fe3+/Cu2+ ions
dc.typeArticle

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