Design, Synthesis, and Characterization of Polyphosphazene Bearing Stable Nitroxide Radicals as Cathode-Active Materials in Li-Ion Batteries

Abstract

A new synthetic strategy is developed for the synthesis of polyphosphazene bearing stable nitroxide radicals as a pendant group. The resulting material is investigated as a cathode-active material for rechargeable lithium-ion batteries that performs 80 mAh g(-1) capacities at a C/2 current density over 50 cycles. Thus, the inorganic-organic hybrid system can be proposed as an alternative cathode-active material with improved performance.