From Tetrahedral Tetraphosphonic Acids E[p-C6H4P(O)(OH)2]4 (E=C, Si) to Porous Cu- and Zn-MOFs with Large Surface Areas

Basit Öğe Kaydı
dc.contributor.authorSchuetrumpf, Alexandra
dc.contributor.authorBulut, Aysun
dc.contributor.authorHermer, Nele
dc.contributor.authorZorlu, Yunus
dc.contributor.authorKirpi, Erdogan
dc.contributor.authorStock, Norbert
dc.contributor.authorYazaydin, A. Ozgur
dc.date.accessioned2025-10-29T11:33:46Z
dc.date.issued2017
dc.departmentFakülteler, Temel Bilimler Fakültesi, Kimya Bölümü
dc.description.abstractThis study describes the porous MOFs Cu(2)H(4)STPPA.2 H2O (1.2 H2O), Zn(2)H(4)STPPA (2) and Zn(2)H(4)MTPPA (3) obtained using the tetrahedral linkers tetraphenylmethane tetrakis-4-phosphonic acid (H(8)MTTPA) and tetraphenylsilane tetrakis-4-phosphonic acid (H(8)STPPA) under solvothermal conditions. X-ray structures reveal 3D frameworks with large assessable voids. The percentage void volumes and the specific BET surface areas of 1 (48.7 %, 794 m(2)/g), 2 (48.1 %, 565 m(2)/g) and 3 (51.3 %, 927 m(2)/g) predicted by molecular simulations are among the highest reported for MOFs derived from phosphonic acids.
dc.description.sponsorshipDeutsche Forschungsgemeinschaft (DFG)
dc.description.sponsorshipTUBITAK grant [212T060]
dc.description.sponsorshipThe Deutsche Forschungsgemeinschaft (DFG) and TUBITAK grant 212T060 are kindly acknowledged for financial support.
dc.identifier.doi10.1002/slct.201700573
dc.identifier.endpage3038
dc.identifier.issn2365-6549
dc.identifier.issue10
dc.identifier.orcid0000-0002-5105-7280
dc.identifier.orcid0000-0003-2811-1872
dc.identifier.orcid0000-0001-8562-723X
dc.identifier.orcid0000-0002-9446-4708
dc.identifier.scopus2-s2.0-85032292972
dc.identifier.scopusqualityQ3
dc.identifier.startpage3035
dc.identifier.urihttps://doi.org/10.1002/slct.201700573
dc.identifier.urihttps://hdl.handle.net/20.500.14854/12557
dc.identifier.volume2
dc.identifier.wosWOS:000398582400022
dc.identifier.wosqualityQ3
dc.indekslendigikaynakWeb of Science
dc.indekslendigikaynakScopus
dc.language.isoen
dc.publisherWiley-V C H Verlag Gmbh
dc.relation.ispartofChemistryselect
dc.relation.publicationcategoryMakale - Uluslararası Hakemli Dergi - Kurum Öğretim Elemanı
dc.rightsinfo:eu-repo/semantics/closedAccess
dc.snmzKA_WOS_20251020
dc.subjectLigand Design
dc.subjectMetal Organic Solids
dc.subjectMOF
dc.subjectOrganophosphonates
dc.titleFrom Tetrahedral Tetraphosphonic Acids E[p-C6H4P(O)(OH)2]4 (E=C, Si) to Porous Cu- and Zn-MOFs with Large Surface Areas
dc.typeArticle

Dosyalar

Koleksiyon

WoS İndeksli Yayınlar Koleksiyonu
Scopus İndeksli Yayınlar Koleksiyonu
Temel Bilimler Fakültesi Koleksiyonu