Alkali Phosphonate Metal-Organic Frameworks

Basit Öğe Kaydı
dc.contributor.authorMaares, Maria
dc.contributor.authorAyhan, M. Menaf
dc.contributor.authorYu, Kai B.
dc.contributor.authorYazaydin, A. Ozgur
dc.contributor.authorHarmandar, Keyser
dc.contributor.authorHaase, Hajo
dc.contributor.authorBeckmann, Jens
dc.date.accessioned2025-10-29T11:34:25Z
dc.date.issued2019
dc.departmentFakülteler, Temel Bilimler Fakültesi, Kimya Bölümü
dc.description.abstractA new family of porous metal-organic frameworks (MOFs), namely alkali phosphonate MOFs, is reported. [Na2Cu(H(4)TPPA)].(NH2(CH3)(2))(2) (GTUB-1) was synthesized using the tetratopic 5,10,15,20-tetrakis[p-phenylphosphonic acid] porphyrin (H-8-TPPA) linker with planar X-shaped geometrical core. GTUB-1 is composed of rectangular void channels with BET surface area of 697 m(2) g(-1). GTUB-1 exhibits exceptional thermal stability. The toxicity analysis of the (H-8-TPPA) linker indicates that it is well tolerated by an intestinal cell line, suggesting its suitability for creating phosphonate MOFs for biological applications.
dc.description.sponsorshipDeutsche Forschungsgemeinschaft [DFG YU 267/2-1, BE 3716/9-1]
dc.description.sponsorshipTurkiye Bilimsel ve Teknolojik Aratrma Kurumu (Tubitak) [117Z383]
dc.description.sponsorshipWe appreciate the funding from Deutsche Forschungsgemeinschaft (DFG YU 267/2-1 and BE 3716/9-1) and Turkiye Bilimsel ve Teknolojik Aratrma Kurumu (Tubitak, Grant No: 117Z383).
dc.identifier.doi10.1002/chem.201902207
dc.identifier.endpage11217
dc.identifier.issn0947-6539
dc.identifier.issn1521-3765
dc.identifier.issue48
dc.identifier.orcid0000-0002-5105-7280
dc.identifier.orcid0000-0002-9140-2448
dc.identifier.orcid0000-0001-8562-723X
dc.identifier.orcid0000-0001-5367-2220
dc.identifier.orcid0000-0003-0709-7266
dc.identifier.pmid31157935
dc.identifier.scopus2-s2.0-85068435943
dc.identifier.scopusqualityQ1
dc.identifier.startpage11214
dc.identifier.urihttps://doi.org/10.1002/chem.201902207
dc.identifier.urihttps://hdl.handle.net/20.500.14854/12855
dc.identifier.volume25
dc.identifier.wosWOS:000474122600001
dc.identifier.wosqualityQ1
dc.indekslendigikaynakWeb of Science
dc.indekslendigikaynakScopus
dc.indekslendigikaynakPubMed
dc.language.isoen
dc.publisherWiley-V C H Verlag Gmbh
dc.relation.ispartofChemistry-A European Journal
dc.relation.publicationcategoryMakale - Uluslararası Hakemli Dergi - Kurum Öğretim Elemanı
dc.rightsinfo:eu-repo/semantics/closedAccess
dc.snmzKA_WOS_20251020
dc.subjectalkali-phosphonate
dc.subjectmetal-organic frameworks
dc.subjectporphyrin
dc.subjectthermal stability
dc.subjecttoxicology
dc.titleAlkali Phosphonate Metal-Organic Frameworks
dc.typeArticle

Dosyalar

Koleksiyon

WoS İndeksli Yayınlar Koleksiyonu
PubMed İndeksli Yayınlar Koleksiyonu
Scopus İndeksli Yayınlar Koleksiyonu
Temel Bilimler Fakültesi Koleksiyonu