Synthesis and EPR studies of soluble vanadyl octakis(4-tert-butylbenzylthio) porphyrazine

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dc.contributor.authorKeskin, Bahadir
dc.contributor.authorYerli, Yusuf
dc.contributor.authorAvciata, Ulvi
dc.date.accessioned2025-10-29T11:17:22Z
dc.date.issued2013
dc.departmentFakülteler, Temel Bilimler Fakültesi, Kimya Bölümü
dc.departmentFakülteler, Temel Bilimler Fakültesi, Fizik Bölümü
dc.description.abstractMagnesium porphyrazinate substituted with eight 4-tert-butylphenylthio-groups on peripheral positions has been synthesized by cyclotetramerization of 1,2-bis(4-t-butylphenylthio)maleonitrile in the presence of magnesium butanolate. The metal-free derivative was obtained by treatment with trifluoroacetic acid and further reaction of this product with vanadyl(IV) sulfate led to the vanadyl porphyrazinate. These new compounds have been characterized by elemental analysis, together with FTIR, and UV-vis spectral data. The magnetic properties of the complex have been investigated by electron paramagnetic resonance spectroscopy.
dc.description.sponsorshipResearch Fund of the Yildiz Technical University [2012-01-02-GEP08]
dc.description.sponsorshipThis work was supported by the Research Fund of the Yildiz Technical University; Project No. 2012-01-02-GEP08.
dc.identifier.doi10.1080/00958972.2013.811496
dc.identifier.endpage2622
dc.identifier.issn0095-8972
dc.identifier.issn1029-0389
dc.identifier.issue15
dc.identifier.orcid0000-0001-8502-8982
dc.identifier.scopus2-s2.0-84880315398
dc.identifier.scopusqualityQ3
dc.identifier.startpage2615
dc.identifier.urihttps://doi.org/10.1080/00958972.2013.811496
dc.identifier.urihttps://hdl.handle.net/20.500.14854/8036
dc.identifier.volume66
dc.identifier.wosWOS:000321814600004
dc.identifier.wosqualityQ2
dc.indekslendigikaynakWeb of Science
dc.indekslendigikaynakScopus
dc.language.isoen
dc.publisherTaylor & Francis Ltd
dc.relation.ispartofJournal of Coordination Chemistry
dc.relation.publicationcategoryMakale - Uluslararası Hakemli Dergi - Kurum Öğretim Elemanı
dc.rightsinfo:eu-repo/semantics/closedAccess
dc.snmzKA_WOS_20251020
dc.subjectPorphyrazine
dc.subjectVanadyl(IV) sulfate
dc.subjectEPR
dc.titleSynthesis and EPR studies of soluble vanadyl octakis(4-tert-butylbenzylthio) porphyrazine
dc.typeArticle

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