Sulfonamide-substituted iron phthalocyanine: design, solubility range, stability and oxidation of olefins

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dc.contributor.authorIsci, Umit
dc.contributor.authorCaner, Celal
dc.contributor.authorZorlu, Yunus
dc.contributor.authorGürek, Ayşe Gül
dc.contributor.authorDumoulin, Fabienne
dc.contributor.authorAhsen, Vefa
dc.date.accessioned2025-10-29T11:20:10Z
dc.date.issued2014
dc.departmentFakülteler, Temel Bilimler Fakültesi, Kimya Bölümü
dc.description.abstract4-tert-Butylbenzenesulfonamide was used as a substituent of tetra peripherally substituted Fe(II) phthalocyanine, taking into account several parameters crucial for the design of potential oxidation catalysts such as solubility and stability. The resulting phthalocyanine exhibits a remarkable stability under oxidative conditions. The main product of the oxidation of cyclohexene using H2O2 as the oxidant is the allylic ketone, 2-cyclohexen-1-one. Styrene oxidation led mainly to the formation of benzaldehyde.
dc.description.sponsorshipScientific and Technological Research Council of Turkey (TUBITAK) [112M370]
dc.description.sponsorshipThe Scientific and Technological Research Council of Turkey (TUBITAK) is gratefully acknowledged for its funding through the project 112M370 coupled to the COST Action CM1205 CARISMA.
dc.identifier.doi10.1039/c4dt02412e
dc.identifier.endpage17919
dc.identifier.issn1477-9226
dc.identifier.issn1477-9234
dc.identifier.issue48
dc.identifier.orcid0000-0002-6285-0524
dc.identifier.orcid0000-0003-2811-1872
dc.identifier.orcid0000-0002-0388-8338
dc.identifier.orcid0000-0002-1252-4093
dc.identifier.pmid25355136
dc.identifier.scopus2-s2.0-84911902120
dc.identifier.scopusqualityQ2
dc.identifier.startpage17916
dc.identifier.urihttps://doi.org/10.1039/c4dt02412e
dc.identifier.urihttps://hdl.handle.net/20.500.14854/8452
dc.identifier.volume43
dc.identifier.wosWOS:000345453700008
dc.identifier.wosqualityQ1
dc.indekslendigikaynakWeb of Science
dc.indekslendigikaynakScopus
dc.indekslendigikaynakPubMed
dc.language.isoen
dc.publisherRoyal Soc Chemistry
dc.relation.ispartofDalton Transactions
dc.relation.publicationcategoryMakale - Uluslararası Hakemli Dergi - Kurum Öğretim Elemanı
dc.rightsinfo:eu-repo/semantics/closedAccess
dc.snmzKA_WOS_20251020
dc.subjectCatalytic-Activity
dc.subjectHomogeneous Solution
dc.subjectHydrogen-Peroxide
dc.subjectAllylic Oxidation
dc.subjectCyclohexene
dc.subjectPorphyrins
dc.subjectBenzene
dc.subjectMethane
dc.titleSulfonamide-substituted iron phthalocyanine: design, solubility range, stability and oxidation of olefins
dc.typeArticle

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