Near-IR-Triggered, Remote-Controlled Release of Metal Ions: A Novel Strategy for Caged Ions

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dc.contributor.authorAtilgan, Ahmet
dc.contributor.authorEcik, Esra Tanriverdi
dc.contributor.authorGuliyev, Ruslan
dc.contributor.authorUyar, T. Bilal
dc.contributor.authorErbas-Cakmak, Sundus
dc.contributor.authorAkkaya, Engin U.
dc.date.accessioned2025-10-29T11:34:34Z
dc.date.issued2014
dc.departmentFakülteler, Temel Bilimler Fakültesi, Kimya Bölümü
dc.description.abstractA ligand incorporating a dithioethenyl moiety is cleaved into fragments which have a lower metal-ion affinity upon irradiation with low-energy red/near-IR light. The cleavage is a result of singlet oxygen generation which occurs on excitation of the photosensitizer modules. The method has many tunable factors that could make it a satisfactory caging strategy for metal ions.
dc.description.sponsorshipTUBITAK [113T043]
dc.description.sponsorshipTUBITAK
dc.description.sponsorshipFunding from TUBITAK (113T043) is gratefully acknowledged. R.G. and T.B.U. acknowledge support from TUBITAK in the form of postdoctoral and doctoral scholarships.
dc.identifier.doi10.1002/anie.201405462
dc.identifier.endpage10681
dc.identifier.issn1433-7851
dc.identifier.issn1521-3773
dc.identifier.issue40
dc.identifier.orcid0000-0003-4720-7554
dc.identifier.orcid0000-0003-4168-8377
dc.identifier.orcid0000-0002-4523-2791
dc.identifier.pmid25130984
dc.identifier.scopus2-s2.0-84928902760
dc.identifier.scopusqualityQ1
dc.identifier.startpage10678
dc.identifier.urihttps://doi.org/10.1002/anie.201405462
dc.identifier.urihttps://hdl.handle.net/20.500.14854/12940
dc.identifier.volume53
dc.identifier.wosWOS:000342761500019
dc.identifier.wosqualityQ1
dc.indekslendigikaynakWeb of Science
dc.indekslendigikaynakScopus
dc.indekslendigikaynakPubMed
dc.language.isoen
dc.publisherWiley-V C H Verlag Gmbh
dc.relation.ispartofAngewandte Chemie-International Edition
dc.relation.publicationcategoryMakale - Uluslararası Hakemli Dergi - Kurum Öğretim Elemanı
dc.rightsinfo:eu-repo/semantics/closedAccess
dc.snmzKA_WOS_20251020
dc.subjectcaged compounds
dc.subjectphotochemistry
dc.subjectphotosensitizers
dc.subjectsinglet oxygen
dc.subjectzinc
dc.titleNear-IR-Triggered, Remote-Controlled Release of Metal Ions: A Novel Strategy for Caged Ions
dc.typeArticle

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