Kinetics and mechanism of methylene blue removal by electrosynthesized ferrate(VI)

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dc.contributor.authorTurkay, Ozge
dc.contributor.authorBarisci, Sibel
dc.contributor.authorDimoglo, Anatholy
dc.date.accessioned2025-10-29T11:17:18Z
dc.date.issued2016
dc.departmentFakülteler, Mühendislik Fakültesi, Çevre Mühendisliği Bölümü
dc.description.abstractThe oxidation of methylene blue (MB) by electrosynthesized ferrate(VI) in a semi-batch reactor is investigated. The effects of pH, Fe(VI) dose and initial MB concentration on the efficiency of the degradation process were studied. The original pH of MB solution was found more effective on the degradation and colour removal as 96.82% MB removal and 40.36% colour removal were gained. Initial MB solution and Fe(VI) dose affected the removal efficiencies. Degradation of MB by Fe(VI) was the second-order reaction kinetics. The density functional theory (DFT) analysis confirmed that density is intended mostly on the phenyl rings and least of all on the bonding orbitals of the middle heterocycle of MB.
dc.identifier.doi10.1080/01496395.2016.1182189
dc.identifier.endpage1931
dc.identifier.issn0149-6395
dc.identifier.issn1520-5754
dc.identifier.issue11
dc.identifier.orcid0000-0003-4229-0408
dc.identifier.scopus2-s2.0-84975258345
dc.identifier.scopusqualityQ2
dc.identifier.startpage1924
dc.identifier.urihttps://doi.org/10.1080/01496395.2016.1182189
dc.identifier.urihttps://hdl.handle.net/20.500.14854/7999
dc.identifier.volume51
dc.identifier.wosWOS:000381286400015
dc.identifier.wosqualityQ3
dc.indekslendigikaynakWeb of Science
dc.indekslendigikaynakScopus
dc.language.isoen
dc.publisherTaylor & Francis Inc
dc.relation.ispartofSeparation Science and Technology
dc.relation.publicationcategoryMakale - Uluslararası Hakemli Dergi - Kurum Öğretim Elemanı
dc.rightsinfo:eu-repo/semantics/closedAccess
dc.snmzKA_WOS_20251020
dc.subjectDegradation
dc.subjectdensity functional theory
dc.subjectferrate(VI)
dc.subjectkinetics
dc.subjectmethylene blue
dc.titleKinetics and mechanism of methylene blue removal by electrosynthesized ferrate(VI)
dc.typeArticle

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