Self assembly of sandwich-layered 2D silver(I) coordination polymers stabilized by argentophilic interactions: Synthesis, crystal structures and ab initio intramolecular energetics

Abstract

Two different two-dimensional silver(I) coordination polymers, namely {[Ag-2(dcpa)}(n) (1) and {[Ag-2(ma)]}(n) (2), where dcpa = 4,5-dichlorophthalate; ma = maleate, were synthesized and structurally analyzed by single crystal X-ray diffraction technique. Complexes 1 and 2 represent 2D coordination polymer with metal organic sandwich type. Two independent Ag(I) ions in both complexes are linked to constructed 2D layer by mu(8)-eta(3):eta(2):eta(2):eta(1) (for complex 1) and mu(8)-eta(3):eta(3):eta(2):eta(2) (for complex 2) carboxylate bridging fashions. The 2D layers of 1 are further extended into a three-dimensional (3D) supramolecular network by weak Cl center dot center dot center dot Cl interactions while 2D layers of 2 are linked by weak CH center dot center dot center dot O interactions into a 3D supramolecular framework. These two complexes exhibit considerable short Ag Ag argentophilic interactions. The long-range corrected density functional theory (DFT) method was used to investigate intramolecular energetics, which are responsible for these 2D structures. Natural bond orbital (NBO) analysis with long-range corrected DFT method assists to understand these intramolecular interactions. (C) 2014 Elsevier B.V. All rights reserved.