Comparison of high-performance liquid chromatography of cyclotriphosphazene derivatives with one or two equivalent stereogenic centres

Basit Öğe Kaydı
dc.contributor.authorBesli, Serap
dc.contributor.authorDavies, David B.
dc.contributor.authorKilic, Adem
dc.contributor.authorShaw, Robert A.
dc.contributor.authorSahin, Sule
dc.contributor.authorUslu, Aylin
dc.contributor.authorYeşilot, Serkan
dc.date.accessioned2025-10-29T11:29:48Z
dc.date.issued2006
dc.departmentFakülteler, Temel Bilimler Fakültesi, Kimya Bölümü
dc.description.abstractHigh-performance liquid chromatographic (HPLC) methods have been developed for investigating the stereogenic properties of two analogous series of dibenzylamino derivatives of cyclotriphosphazene containing either one or two equivalent stereogenic centres. Separation of the enantiomers of all the racemic compounds has been investigated by chiral HPLC using Whelk-01 and Chiralcel OD columns. In all cases, conditions for separation of enantiomers have been found using a Whelk-01 column with different ratios of tetrahydrofuran in n-hexane as the mobile phase. It is found that both the separation factor (alpha) and resolution factor (R-S) of molecules with two equivalent stereogenic centres are greater than those for analogues with only one centre. (c) 2006 Elsevier B.V. All rights reserved.
dc.identifier.doi10.1016/j.chroma.2006.07.094
dc.identifier.endpage205
dc.identifier.issn0021-9673
dc.identifier.issn1873-3778
dc.identifier.issue1-2
dc.identifier.orcid0000-0003-2181-2457
dc.identifier.pmid16965786
dc.identifier.scopus2-s2.0-33749523359
dc.identifier.scopusqualityQ1
dc.identifier.startpage201
dc.identifier.urihttps://doi.org/10.1016/j.chroma.2006.07.094
dc.identifier.urihttps://hdl.handle.net/20.500.14854/11259
dc.identifier.volume1132
dc.identifier.wosWOS:000241538400023
dc.identifier.wosqualityQ1
dc.indekslendigikaynakWeb of Science
dc.indekslendigikaynakScopus
dc.indekslendigikaynakPubMed
dc.language.isoen
dc.publisherElsevier
dc.relation.ispartofJournal of Chromatography A
dc.relation.publicationcategoryMakale - Uluslararası Hakemli Dergi - Kurum Öğretim Elemanı
dc.rightsinfo:eu-repo/semantics/closedAccess
dc.snmzKA_WOS_20251020
dc.subjectenantiomers
dc.subjectchiral HPLC
dc.subjectwhelk-01 column
dc.subjectcyclotriphosphazene derivatives
dc.titleComparison of high-performance liquid chromatography of cyclotriphosphazene derivatives with one or two equivalent stereogenic centres
dc.typeArticle

Dosyalar

Koleksiyon

WoS İndeksli Yayınlar Koleksiyonu
PubMed İndeksli Yayınlar Koleksiyonu
Scopus İndeksli Yayınlar Koleksiyonu
Temel Bilimler Fakültesi Koleksiyonu